NANOSTRUCTURED FILMS OF PLASMA POLYMERIZED HEXAMETHYLDISILAZANE AND LACTIC ACID DEPOSITED BY ATMOSPHERIC PLASMA JET

1 KRTOUŠ Zdeněk
Co-authors:
2 NIKIFOROV Anton 2 KUCHAKOVA Iryna 3 KOLÁŘOVÁ-RAŠKOVÁ Zuzana 3,4 SEDLAŘÍKOVÁ Jana 1 KRETKOVÁ Tereza 1 KUŠ Peter 1 KYLIÁN Ondřej 1 KOUSAL Jaroslav
Institutions:
1 Charles University, Faculty of Mathematics and Physics, Prague, Czech Republic
2 Faculty of Engineering and Architecture, Ghent University, Ghent, Belgium
3 Tomas Bata University in Zlin, Centre of Polymer Systems, Zlin, Czech Republic
4 Tomas Bata University in Zlin, Faculty of Technology, Zlin, Czech Republic
Conference:
11th International Conference on Nanomaterials - Research & Application, Hotel Voronez I, Brno, Czech Republic, EU, October 16th - 18th 2019
Proceedings:
Proceedings 11th International Conference on Nanomaterials - Research & Application
Pages:
368-373
ISBN:
978-80-87294-95-6
ISSN:
2694-930X
Published:
1st April 2020
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
873 views / 375 downloads
Abstract

In this work, composite layers of hexamethyldisilazane (HMDSN) and lactic acid (LA) were prepared using chemical vapor deposition process by a nitrogen atmospheric pressure plasma jet source. The HMDSN vapours were introduced into the plasma jet. Varying LA admixture was added into the jet in the form of aerosol.The chemical composition, morphology and wettability of resulting films were studied. Infrared spectra and XPS analysis show both SiO like and hydrocarbon structures. With increasing amount of LA admixture, the oxidation of the layers increases. The morphology of the films was measured with SEM. The films prepared with no LA have a foam-like structure. With increasing amount of LA the structure changes into more fractal-like. The Xray diffraction analysis suggests the presence of amorphous SiO2 domains in the films. The films exhibited superhydrophobic properties that can be modified by the posttreatment of the samples in DBD discharge.

Keywords: lactic acid, hexamethyldisilazane, atmospheric plasma jet

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