EXPERIMENTAL EVALUATION OF AGRICULTURAL BIOMASS-BASED REDUCTANT FOR SUSTAINABLE FERROALLOY SMELTING

1 SAKUNEKA Sewela
Co-authors:
1 WA KALENGA Michel 1 NHETA Willie
Institution:
1 Mineral Processing and Technology Research Centre, Department of Metallurgy, University of Johannesburg, P.O. Box 17011, Doornfontein 2028, South Africa, sewela.sakuneka@gmail.com, michelk@uj.ac.za, wnheta@uj.ac.za
Conference:
34th International Conference on Metallurgy and Materials, Orea Congress Hotel Brno, Czech Republic, EU, May 21 - 23, 2025
Proceedings:
Proceedings 34th International Conference on Metallurgy and Materials
ISBN:
978-80-88365-27-3
ISSN:
2694-9296
Licence:
CC BY 4.0
Metrics:
27 views / 18 downloads
Abstract

The South African ferroalloy industry faces increasing environmental pressures to transition toward sustainable metallurgical practices. Traditional smelting relies heavily on fossil-based reductants and fluxing agents, contributing significantly to carbon emissions. This study investigates the capabilities of macadamia nutshell biochar as an alternative reductant in ferromanganese production. High-grade manganese ore was crushed and pulverized to ~75 μm. Its mineralogy was analyzed through X-ray diffraction (XRD), while scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM/EDS) and X-ray fluorescence (XRF) characterized its chemical composition, Macadamia nutshells were pyrolyzed at 700 °C for 45 minutes under an argon atmosphere to produce biochar, which was characterized using proximate and ultimate analysis. Reduction experiments were performed in an alumina tube furnace at 1300 °C under argon using a graphite crucible to assess the biochar’s effectiveness as a reductant. Preliminary results showed great that the use of macadamia biochar as an alternative reductant to produce high carbon ferromanganese production can be effective if thoroughly investigated. Also, the raw macadamia nutshell conversion to biochar was successful with fixed carbon reaching 85.97%.

Keywords: Biomass, macadamia nutshells, pyrolysis, metal recovery, ferromanganese

© This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Scroll to Top