INVESTIGATION ON POSSIBLE USE OF PALM NUTSHELLS AS REDUCTANT FOR THE REDUCTION OF COPPER SLAG FOR COPPER RECOVERY

1 WA KALENGA Michel Kalenga
Co-authors:
1 THUNKA Motshoea 1 NYEMBWE Didier Kasongo
Institution:
1 Department of metallurgy, School of mining, metallurgy and chemical engineering, Faculty of Engineering and Built Environment, University of Johannesburg, Doornfontein, South Africa, michelk@uj.ac.za
Conference:
29th International Conference on Metallurgy and Materials, Brno, Czech Republic, EU, May 20 - 22, 2020
Proceedings:
Proceedings 29th International Conference on Metallurgy and Materials
Pages:
948-953
ISBN:
978-80-87294-97-0
ISSN:
2694-9296
Published:
27th July 2020
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
643 views / 391 downloads
Abstract

The depletion of ores from the first sources on one hand has led to using damped materials that contain valuable metals to be recycled while environmental threats are being targeted and on the other hand high price of reductant coupled with their depletion have caused a stir in the metallurgical industry. Many slags are currently recycled for the recovery of valuable metals while new reductants are being tested for eventually replace the generic reductants. In this work, copper slag from Water-jacket furnace have been used to recover copper in presence of raw palm nutshells as possible replacement of generic reductants. Characterisation of the copper slag, the palm nutshells and products were conducted using XRD, XRF and SEM-EDS. Results have shown that dominants elements in the slag were Fe 33.83 wt%, Zn 6.73 wt%, Cu 1.26 wt%. Raw palm nutshells analyses revealed 6.39 wt% moisture, 61.56 wt% volatile matters and 4.35 wt% ash content while fixed carbon amounted to be 27.89 % and loss of ignition (LOI) 91.8 %. The reduction experiments were conducted in a horizontal tube furnace at 1300 °C under argon to create an inert environment and efficiently test the reducing capability of the palm nutshells. The composition of the metal produced revealed 41.84 wt% Cu, 26.41 wt% Co and 31.75 wt% Fe. However, it was noticed that the miscibility of the metal and the slag was prominent. As a first attempt, results showed very promising and further investigations are required to reveal optimums conditions.

Keywords: Metallurgy, palm nutshells, reductant, slag

© This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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