CORROSION PRODUCTS PHASE IDENTIFICATION USING MICRO-RAMAN AND FTIR

1,2 MAJTÁS Dušan
Co-authors:
1 MÁCOVÁ Petra
Institutions:
1 Institute of Theoretical and Applied Mechanics, Prague, Czech Republic, EU, majtas@itam.cas.cz
2 Faculty of Sciences, Department of Chemistry, Masaryk University, Brno, Czech Republic, EU
Conference:
27th International Conference on Metallurgy and Materials, Hotel Voronez I, Brno, Czech Republic, EU, May 23rd - 25th 2018
Proceedings:
Proceedings 27th International Conference on Metallurgy and Materials
Pages:
772-776
ISBN:
978-80-87294-84-0
ISSN:
2694-9296
Published:
24th October 2018
Proceedings of the conference were published in Web of Science and Scopus.
Metrics:
13 views / 6 downloads
Abstract

Phase identification of corroded metal objects might be problematic because corrosion products are usually a complex mixture of different phases. Furthermore, some of present phases may be either semi-crystalline or amorphous. The most suitable procedure is to use X-ray diffraction (XRD), for identification of crystalline phases in bulk, in combination with micro-Raman spectroscopy to obtain information on smaller scale and given location. Micro-Raman spectroscopy identifies crystalline and semi-crystalline phases. The literature also reports of the application of Mössbauer spectroscopy to identify amorphous phases. In this work, the combined use of Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy is evaluated. The methods may be interchangeable to some point. But is it safe to assume that all phases present can be detected?

Keywords: Corrosion, micro-Raman spectroscopy, FTIR
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